Crossed intramolecular Rauhut-Currier-type reactions via dienamine activation.
نویسندگان
چکیده
The intramolecular Rauhut-Currier reaction creates a carbon-carbon bond between two tethered Michael acceptors. Previous asymmetric versions have relied on 1,4-additions of chiral nucleophilic catalysts. Herein, we investigate a novel strategy that involves the formation of electron rich dienamines as key intermediates. Our methodology provides an efficient entry to the iridoid framework.
منابع مشابه
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عنوان ژورنال:
- Organic letters
دوره 11 18 شماره
صفحات -
تاریخ انتشار 2009